Here is some information that I found on Alexandrine on the Peerage.com website:
"Countess Alexandrine Hutten-Czapska
b. 3 September 1854, d. 8 May 1941,
Countess Alexandrine Hutten-Czapska was the daughter of Count Adam Hutten-Czapsky and Countess Marianne Rzewuska. She was born on 3 September 1854 at Warsaw, Poland.
She married, firstly, Alexander von Kolemine on 2 February 1873. She and Alexander von Kolemine were divorced in March 1884.
She married, secondly, Basil von Bacheracht after 1884.
She married, thirdly, Ludwig IV Friedrich Wilhelm Karl Großherzog von Hessen und bei Rhein (of the House of Hesse), son of Karl Wilhelm Ludwig Prinz General von Hessen und bei Rhein (of the House of Hesse) and Marie Elisabeth Caroline Viktoria Prinzessin von Preußen (of the House of Hohenzollern), on 30 April 1884 at Darmstadt, Hessen, Germany. She and Ludwig IV Friedrich Wilhelm Karl Großherzog von Hessen und bei Rhein (of the House of Hesse) were divorced on 9 July 1884.
She died on 8 May 1941 at age 86 at Vevey, Switzerland. She gained the title of Countess von Romrod on 31 May 1884."