I haven't read this book, so I do not know if it can be recommended, but the subject fits:
"Воспитание православного государя в Доме Романовых" (The education of an Orthodox monarch in the House of Romanov), by Marina Evtushenko.
ISBN 978-5-496-01556-1
The description of the book provided by the publisher includes the typical West-bashing, in this case directed against the evil Brits (the USA weren't yet a world power), who infected the young future tsar Alexander I with anglophilia. But I suppose that is a compulsory feature in every book published in Putin's Russia.
"In the book "The Education of a Orthodox monarch in the House of Romanov", you can learn:
How were Orthodox monarchs educated?
What were the bases of this unique system of education?
Who taught our tsars?
What were the consequences of miscalculation and errors in their education, and what came out of them?"
http://www.ozon.ru/context/detail/id/32020181/