Many of the coutiers' memoirs mention Tatiana's looks, and how they contrasted with her sisters'.
Gilliard:
The second girl, Tatiana, was eight and a half. She had auburn hair and was prettier than her sister, but gave one the impression of being less transparent, frank, and spontaneous.
She was very pretty, though she had not quite Olga Nicolaievna's charm....Through her good looks and her art of self-assertion she put her sister in the shade in public...
Buxhoeveden:
Tatiana Nicolaevna was to my mind prettier than her sisters. She was taller even than the Empress, but she was so slight and well-proportioned that her great height was not remarkable. She had fine, regular features, recalling pictures of ancestresses who had been famous beauties. She had dark hair, a rather pale complexion, and wide-apart, light-brown eyes, that gave her a poetic far-away look, not quite in keeping with her character.
Dehn:
She was very tall, and excessively thin, with a cameolike profile, deep blue eyes, and dark chestnut hair... a lovely Rose maiden, fragile and pure as a flower.
Vyrubova:
Tatiana was almost a perfect reincarnation of her mother. Taller and slenderer than her sisters, she had the soft, refined features and the gentle, reserved manners of her English ancestry....Certainly she was a different type from the others even in appearance, her hair being a rich brown and her eyes so darkly gray that in the evening they seemed quite black.